纳米多孔材料
2004-12
World Scientific Pub Co Inc
Lu, G. Q. (EDT)/ Zhao, X. S. (EDT)
897
Porous materials are of scientific and technological importance because of the presence of voids of controllable dimensions at the atomic, molecular, and nanometer scales, enabling them to discriminate and interact with molecules and clusters. Interestingly the big deal about this class of materials is about the "nothingness" within — the pore space. International Union of Pure and Applied Chemistry (IUPAC) classifies porous materials into three categories — micropores of less than 2 nm in diameter, mesopores between 2 and 50 nm, and macropores of greater than 50 nm. In this book, nanoporous materials are defined as those porous materials with pore diameters less than 100 nm. Over the last decade, there has been an ever increasing interest and research effort in the synthesis, characterization, functionalization, molecular modeling and design of nanoporous materials. The main challenges in research include the fundamental understanding of structure-property relations and tailor-design of nanostructures for specific properties and applications. Research efforts in this field have been driven by the rapid growing emerging applications such as biosensor, drug delivery, gas separation, energy storage and fuel cell technology, nanocatalysis and photonics. These applications offer exciting new opportunities for scientists to develop new strategies and techniques for the synthesis and applications of these materials. This book provides a series of systematic reviews of the recent developments in nanoporous materials. It covers the following topics: (1) synthesis, processing, characterization and property evaluation; (2) functionalization by physical and/or chemical treatments; (3) experimental and computational studies on fundamental properties, such as catalytic effects, transport and adsorption, molecular sieving and biosorption; (4) applications, including photonic devices, catalysis, environmental pollution control, biological molecules separation and isolation, sensors, membranes, hydrogen and energy storage, etc.
Chapter 1 Nanoporous Materials-An OverviewChapter 2 Advances in Mesoporous Materials Templated by Nonionic Block CopolymersChapter 3 Zeolite/Mesoporous Molecular Sieve Composite MaterialsChapter 4 Chromium-Containing Ordered Nanoporous MaterialsChapter 5 Surfactant-Templated Mesostructured Materials: Synthesis and Compositional ControlChapter 6 Organic Host-Guest Structures in the Solid StateChapter 7 Nonsurfactant Route to Nanoporous Phenyl-Modified Hybrid Silica MaterialsChapter 8 3D Macroporous Photonic Materials Templated by Self Assembled Colloidal SpheresChapter 9 Hydrophobic Microporous Silica Membranes for Gas Separation and Membrane ReactorsChapter 10 Synthesis and Characterization of Carbon Nanotubes for Hydrogen StorageChapter 11 Physical Adsorption Characterization of Ordered and Amorphous Mesoporous MaterialsChapter 12 Molecular Simulation of Adsorption in Porous MaterialsChapter 13 Surface Functionalization of Ordered Nanoporous SilicatesChapter 14 Surface Alumination of Mesoporous SilicatesChapter 15 Acidity Measurement of Nanoporous Aluminosilicates - Zeolites and MCM-41Chapter 16 Nanocatalysts Prepared by the Molecularly Designed Dispersion ProcessChapter 17 Acidity-enhanced Nanoporous Catalytic MaterialsChapter 18 Modified Mesoporous Materials as Acid and Base CatalystsChapter 19 Lewis Acid/Base Catalysts Supported on Nanoporous Silica as Environmental CatalystsChapter 20 Nanoporous Catalysts for Shape-Selective Synthesis of Specialty Chemicals:A Review of Synthesis of 4,4'-DialkylbiphenylChapter 21 Catalysis Involving Mesoporous Molecular SievesChapter 22 Adsorption and Transport in Nanoporous MaterialsChapter 23 Adsorption of Organic Molecules in Nanoporous Adsorbents from Aqueous SolutionChapter 24 Functionalized Nanoporous Adsorbents for Environmental RemediationChapter 25 Nanoporous Adsorbents for Air Pollutant RemovalChapter 26 Bioadsorption and Separation with Nanoporous MaterialsChapter 27 Nanoporous Materials as Supports for Enzyme ImmobilizationChapter 28 A Novel Non-surfactant Route to Nanoporous Materials and its Biological Applications
