有机合成现代方法
2008-10
世界图书出版公司
卡如萨
493
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This book is addressed principally to advanced undergraduates and to graduates at the beginning of their research careers, and aims to bring to their notice some of the reactions used in modern organic syntheses. Clearly, the whole field of synthesis could not be covered in a book of this size, even in a cursory manner, and a selection has had to be made. This has been governed largely by consideration of the usefulness of the reactions, their versatility and, in some cases, their selectivity.
The fourth edition of this well-known textbook discusses the key methods used inorganic synthesis, showing the value and scope of these methods and how they areused in the synthesis of complex molecules. All the text from the third edition hasbeen revised, to produce a modem account of traditional methods and an up-to-datedescription of recent advancements in synthetic chemistry. The textbook maintainsa traditional and logical approach in detailing carbon--carbon bond formations,followed by a new chapter on the functionalization of alkenes and concluding withoxidation and reduction reactions. Reference style has been improved to includefootnotes, allowing easy and rapid access to the primary literature. In addition, aselection of problems has been added at the end of each chapter, with answersat the end of the book. The book will be of significant interest to chemistry andbiochemistry students at advanced undergraduate and graduate level, as well asto researchers in academia and industry who wish to familiarize themselves withmodem synthetic methods.
作者：(英国)卡如萨 (Carruthers.W.)
Preface to the first editionPreface to the fourth edition1 Formation of carbon-carbon single bonds 1.1 Main-group chemistry 1.1.1 Alkylation of enolates and enamines 1.1.2 Conjugate addition reactions of enolates and enamines 1.1.3 The aldol reaction 1.1.4 Asymmetric methodology with enolates and enamines 1.1.5 Organolithium reagents 1.1.6 Organomagnesium reagents 1.1.7 Organozinc reagents 1.1.8 Allylic organometallics of boron, silicon and tin 1.2 Transition-metal chemistry Problems 1.2.1 Organocopper reagents 1.2.2 Organochromium chemistry 1.2.3 Organocobalt chemistry 1.2.4 Organopalladium chemistry2 Formation of carbon-carbon double bonds 2.1 B-Elimination reactions 2.2 Pyrolytic syn eliminations 2.3 Fragmentation reactions 2.4 Alkenes from hydrazones 2.5 Alkenes from 1,2-diols 2.6 Alkenes from alkynes 2.7 The Wittig and related reactions 2.8 Alkenes from sulfones 2.9 Alkenes using titanium or chromium reagents 2.10 Alkene metathesis reactions Problems3 Pericyclic reactions 3.1 The Diels-Alder cycloaddition reaction 3.1.1 The dienophile 3.1.2 The diene 3.1.3 Regiochemistry of the Diels-Alder reaction 3.1.4 Stereochemistry of the Diels-Alder reaction 3.1.5 Intramolecular Diels-Alder reactions 3.1.6 The retro Diels-Alder reaction 3.1.7 Asymmetric Diels-Alder reactions 3.2 [2+2] Cycloaddition reactions 3.3 Cycloaddition reactions with allyl cations and allyl anions 3.4 1,3-Dipolar cycloaddition reactions 3.5 The ene reaction 3.6 [3,3]-Sigmatropic rearrangements 3.6.1 The Cope rearrangement 3.6.2 The Claisen rearrangement 3.7 [2,3]-Sigmatropic rearrangements 3.8 Electrocyclic reactions Problems4 Radical and carbene chemistry 4.1 Radicals 4.1.1 Radical abstraction reactions 4.1.2 Radical addition reactions 4.2 Carbenes Problems5 Functionalization of alkenes 5.1 Hydroboration 5.1.1 Reactions of organoboranes 5.2 Epoxidation and aziridination 5.2.1 Epoxidation 5.2.2 Asymmetric epoxidation 5.2.3 Aziridination……6 Oxidation7 ReductionAnswers to problemsIndex
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《有机合成现代方法(第4版)》为经典英文化学教材系列之一，由世界图书出版公司出版。
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经典书籍，讲课备课常会用到，文献新颖，可读性强。
不错，值得好好看
书是很不错， 但是化东理工已经有翻译版了。
内容很好，纸质一般！
语言简单，详略得当，适合初级及中级学者。
书的内容很不错，可是书是盗版的，纸不好，有的页面折了好几道，很脏………………╮(╯▽╰)╭